The mass transfer coefficient of an industrial electrowinning cell under different operating conditions

Authors

yazd university, yazd, iran

Abstract

Electrowinning is the process of copper deposing from the intracellular electrolyte solution to the cathode. In the present study, using electrodynamic cell simulation of the Miduk Copper Complex, mass transfer coefficient on the entire cathode surface are investigated. The hydrodynamic simulation of these cells in the Miduk Copper Complex is studied using computational fluid dynamics. Ansys-CFX is used for this modeling. The Navier-Stokes equations and the continuum are considered as two-phase liquid and gas, turbulent, incompressible, and steady state, and the equation for the concentration of copper in the electrolyte will be solved by considering its specific boundary condition. The perturbation of the flow will be modeled using k-ω relations. The cathode mass transfer coefficient of the industrial copper cell was evaluated by measuring the copper mass of the cathode sheets produced in each cell and the operating conditions of the cell under real conditions. The results show 1.9% difference between the actual amount in copper and the modeling value

Keywords

Main Subjects


 
[1] Al Shakarji, R., "Mechanisms of Acid Mist Formation in Electrowinning", Ph. D. Thesis, James Cook University, Australia, Townsville, (2012).
 
[2] Sigrist, L., and Dossenbach, O., "Mass Transport in Electrolytic Cells with Gas Sparging", International Journal Heat and Mass Transfer, Vol. 22, pp. 1393-1399, (1979).
 [3] Raju, G. J. V. J., Venkateswarlu, P., Rao, S. S., and Sarma, C. B., "Effect of Longitudinal Distance of Electrode on the Ionic Mass Transfer on the Confining Wall of a Stirred Vessel", Indian J. Technol., Vol. 5, pp. 400-401, (1979).
 
[4] Raju C. R., Raju, G. J., and Rao, C. V., "Effect of Pulsation on Mass Transfer Coefficients Ionic Mass Transfer", Indian Journal of Technology, Vol. 5, pp. 30-34, (1967).
 
[5] Fisher, K. G., and Hughes, R. G., "Application of Periodic Current Reversal (P.C.R.) to Electrolytic Copper Refining at Mufulira", Trans. Inst. Min. Metall, Vol. 80, pp. 250-261,   (1971).
 
[6] Rao V. P., "Mass Transfer Cylinders Rotating about Parallel Axes", Ph. D. Thesis, Andhra University, Visakhapatnam, India, (1974).
 
[7] Subbaiah T., Venkateswarlu, P., Das, R. P., and Raju, G. J. V. J., "Mass Transfer Conditions at a Cathode Support Plate in an Electrochemical Cell", Chemical Engineering Processing: Process Intensification, Vol. 34, No. 6, pp. 495-501, (1995).
 
[8] Taha, A. A., "Effect of Surfactants on the Rate of Solid Liquid Mass Transfer with Gas Generation at the Interface", Journal of Colloid and Interface Science, Vol. 275, No. 1, pp. 235-242, (2004).
 
[9] Graydon, J., and Kirk, D., "Suspension Codeposition in Electrowinning Cells: The Role of Hydrodynamics", Can. J. Chem. Eng, Vol. 69, pp. 564-570, (2001).
 
[10] Najim, S. T., "Estimation of Mass Transfer Coefficient for Copper Electrowinning Process", Journal of Engineering, Vol. 22, pp. 158-168, (2016).
 
[11] Beukes, N. T., and Badenhorst, J., "Copper Electrowinning: Theoretical and Practical Design", Presented at the Hydrometallurgy Conference 2009, The Southern African Institute of Mining and Metallurgy, Johannesburg, South Africa, (2009).
 
 [12] Cifuentes, L., and Arriagada, P., "Copper Electrowinning in a Moving-bed Cell Based on Reactive Electrodialysis", Revista de Metalurgia, Vol. 44, pp. 151-161, (2008).
 
[13] Najminoori, M., Mohebbi, A., Afrooz, K., and Arabi, B. G., "The Effect of Magnetic Field and Operating Parameters on Cathodic Copper Winning in Electrowinning Process", Chemical Engineering Science, Vol. 199, pp. 1-19, (2019).
 
[14] Soliman, H., and El-Moneim A. A., "Electrowinning of Copper using Rotating Cylinder Electrode Utilizing Lead Anode", Scientific Research, Vol. 3, pp. 340-358, (2011).
 
[15] Coleman, S., and Roy, S., "Effect of Ultrasound on Mass Transfer during Electrodeposition for Electrodes Separated by a Narrow Gap", Chemical Engineering Science, Vol. 113, pp. 35-44, (2014).
 
[16] Filzwieser, A., "Modelling of the Processes Close to Cathodes in Copper Electrolysis (Modellierung der Kathodennahen Vorgänge in der Kupferelektrolyse)", Ph. D. Thesis, Montanuniversität Leoben, University of Leoben, Austria, (2000).
 
[17] Filzwieser, A., Hein, K., and Mori, G., "Current Density Limitation and Diffusion Boundary Layer Calculation using CFD Method", JOM, Vol. 54, pp. 28-31, (2002).
 
[18] Leahy, M. J., and Schwarz, M. P., "Experimental Validation of a Computational Fluid Dynamics Model of Copper Electrowinning", Metallurgical and Materials Transactions B, Vol. 41, pp. 1247-1260, (2010).
 
[19] Schwarz M. P., "Improving Zinc Processing using Computational Fluid Dynamics Modelling Successes and Opportunities", Minerals Engineering, Vol. 30, pp. 12-18, (2012).
 
[20] Leahy, M. J., and Schwarz, M. P., "Flow and Mass Transfer Modelling for Copper Electrowinning: Development of Instabilities along Electrodes", Hydrometallurgy, Vol. 147-148, pp. 41-53, (2014).
 
[21] Najminoori, M., Mohebbi, A., Arabi, B. G., and Daneshpajouh, S., "CFD Simulation of an Industrial Copper Electrowinning Cell", Hydrometallurgy, Vol. 153, pp. 88-97, (2015).
 
[22] Pourahmadi, S. A. A., and Talebi, S., "Hydrodynamic Simulation of Two Phase Flow in an Industrial Electrowinning Cell", Modares Mechanical Engineering, Vol. 20, No. 1, pp. 1-12, (2020).
 
[23]"ANSYS CFX-Solver Theory Guide, Release 15", ed, (2016).
 
[24] König, J., Mühlenhoff, S., Eckert K., Büttner, L., Odenbach, S., and Czarske, J., "Velocity Measurements Inside the Concentration Boundary Layer During Copper-magneto-Electrolysis using a Novel Laser Doppler Profile Sensor", Electrochimica Acta, Vol. 56, No. 17, pp. 6150-6156, (2011).
 
[25] Geankoplis, C. J., "Transport Processes and Separation Process Principles: (Includes Unit Operations)", Prentice Hall Professional Technical Reference, Pearson Education Limited, London, United Kingdom, (2003).
 
[26] Gendron, A., and Ettel, V., "Hydrodynamic Studies in Natural and Forced Convection Electrowinning Cells", The Canadian Journal of Chemical Engineering, Vol. 53, No. 1, pp. 36-40, (1975).
 
[27] Werner, J.M., "Modeling and Validation for Optimization of Electrowinning Performance", Ph.D. Thesis, The University of Utah, Salt Lake City, Utah, United States, (2017).
 
[28] Sutherland, W., "The Viscosity of Gases and Molecular Force", Philosophical Magazine, Vol. 36, pp. 507-531, (1893).
 
[29] Moats, M. S., Hiskey, J. B., and Collins, D. W., "The Effect of Copper, Acid, and Temperature on the Diffusion Coefficient of Cupric Ions in Simulated Electrorefining Electrolytes", Hydrometallurgy, Vol. 56, No. 3, pp. 255-268, (2000).
 
[30] Pourtousi, M., Sahu, J., Ganesana, P., Shamshirband, S., and Redzwan, G., "A Combination of Computational Fluid Dynamics (CFD) and Adaptive Neuro-fuzzy System (ANFIS) for Prediction of the Bubble Column Hydrodynamics", Powder Technology, Vol. 274, pp. 466-481, (2015).
 
[31] Rigby, G.D., Grazier, E.P., Stuart, A.D., and Smithson, E.P., "Gas Bubble Induced Mixing in Electrowinning Baths", Vol. 56, No. 21-22, pp. 6329-6336, (2001).
 
 
Volume 22, Issue 2 - Serial Number 59
Fluid Mechanics and Heat Transfer
June 2020
Pages 103-130
  • Receive Date: 30 November 2019
  • Revise Date: 03 February 2020
  • Accept Date: 08 November 2020